Journal of Japan Oil Chemists' Society
Online ISSN : 1884-2003
ISSN-L : 0513-398X
The Reaction of Carboxylic Acids, Esters, and Acid Anhydrides with Various Alkenylmagnesium Bromides
Shoji WATANABETsutomu FUJITAKyoichi SUGANorio SAITO
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1977 Volume 26 Issue 5 Pages 291-294

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Abstract
The reaction of carboxylic acids, esters, and acid anhydrides with alkenylmagnesium bromide yields mixtures of alkenones and alkenols as the main products. The reaction of vinylmagnesium bromide gives similar results to that of vinylmagnesium chloride. The reactions of isopropenylmagnesium bromide or 1-propenylmagnesium bromide with acids, esters, and anhydrides produce mainly isopropenyl ketones.
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