Journal of Japan Oil Chemists' Society
Online ISSN : 1884-2003
ISSN-L : 0513-398X
Tricarboxylic Acid Biosurfactant Derived from Spiculisporic Acid
Young Kook CHOIChoul Ho LEEYasuomi TAKIZAWAYasuo GAMAYutaka ISHIGAMI
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JOURNAL FREE ACCESS

1993 Volume 42 Issue 2 Pages 95-99

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Abstract
2- (2-Carboxyethyl) -3-decylmaleic acid (DCMA) was derived from spiculisporic acid [(4 S, 5 S) -4, 5-dicarboxy-4-pentadecanolide] produced by biosynthesis using Penicillium spiculisporum No. 10-1 of microbial origin. The sodium and organic amine salts of DCMA were prepared and their surface active properties were studied. Metal ion sequestration and pH buffering capacity were scrutinized. DCMA-diargininate was found to possess a distinct surface active characteristics and DCMA trisodium salt, to have the same biodegradability as soap. The buffering capacity of the sodium salts of DCMA was superior to that of spiculisporic acid sodium salts. It was also observed that DCMA trisodium salt appeared effective as a masking agent or metal chelating agent based on the result of the metal sequestration experiment and IR analysis.
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