Journal of the Physical Society of Japan
Online ISSN : 1347-4073
Print ISSN : 0031-9015
ISSN-L : 0031-9015
Percolation Approach to the Barrier-Controlled Conductivity of Ceramic Composites
Igor P. ZvyaginWataru Kinase
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1995 年 64 巻 8 号 p. 2988-2993

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The temperature and composition dependence of thebarrier-controlled conductivity of two-phase composites is analysedreducing the problem to that of the site-bond percolation. It is shownthat the critical barrier height depends on the volume fraction φof the conducting phase, this giving rise to a specific φ-dependence of the activation energy of the conductivity near thepercolation threshold. Approximate relations suggested for the phaseboundary function of the site-bond problem make it possible toevaluate the distribution of inter-grain barrier characteristics fromthe measurements of the temperature and composition dependence of theconductivity near the percolation threshold.
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© The Physical Society of Japan 1995
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