Journal of the Physical Society of Japan
Online ISSN : 1347-4073
Print ISSN : 0031-9015
ISSN-L : 0031-9015
Dielectric Properties of an Immiscible Polymer Blend with Electrorheological Effect
Hiroshi OriharaMasaru SugayaKozo TajiriYoshihiro IshibashiMasao DoiAkio Inoue
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1998 年 67 巻 2 号 p. 655-657

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Dielectric measurement was carried out on an immiscible blend of a side-chain type polysiloxane liquid crystalline polymer (LCP) and a poly-dimethylsiloxane (PDMS), which has a large electrorheological (ER) effect, in the frequency range from 100, Hz to 10, MHz and over the temperature range from 25°C to 105°C. Two relaxation processes were observed; one is due to the mesogenic motion, i.e., the δ -process of LCP and the other to the Maxwell-Wagner effect originating in the conductivity of LCP dispersed in PDMS. The results were analyzed in terms of the Clausius-Mossotti (CM) approximation and the local field exerted on droplets of LCP was discussed.
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© The Physical Society of Japan 1998
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