Journal of the Physical Society of Japan
Online ISSN : 1347-4073
Print ISSN : 0031-9015
ISSN-L : 0031-9015
Polarizabilities and Shielding Factors of Ions in Cesium Halide Crystals with the Cesium-Chloride Structure
Rahman Md. MahbubarYoshitaka MichihiroKoichi NakamuraTatsuo Kanashiro
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2001 年 70 巻 8 号 p. 2382-2386

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The calculated results of the polarizabilities and the quadrupole shielding factor of the ions in cesium halide crystals with the cesium-chloride structure are presented. The calculation is done on the basis of the self-consistent field local density approximation and the modified Sternheimer equation. The crystalline potential is treated by the spherical solid model. The size effect is seen in the values of the polarizabilities and the quadrupole shielding factor. The values of the polarizabilities and the quadrupole shielding factor of cesium ion show only slight change in different crystals. The values of chlorine ion show significant reduction and the amount of the reduction is different in the different crystals. The effect of the crystalline environment on the electron states is discussed.
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© The Physical Society of Japan 2001
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