1960 Volume 15 Issue 2 Pages 288-296
A study of the Cl35 resonance spectrum was carried out at the room temperature on a single crystal of 1, 3, 5-trichlorobenzene. Spatial orientation of the C–Cl bonds was determined to the accuracy of 1° . An orthorhombic structure was concluded, with the unit cell containing at least four equivalent molecules oriented with the symmetry of D2h. The angles between the C–Cl bonds in each molecule were close to the hexagonal angle, but one of the C–Cl bonds was deformed by ca. 1.6° from the plane of the other two. The asymmetry parameters were observed to be 0.093, 0.111, and 0.129 for three absorption lines, 35.020 Mc, 35.296 Mc, and 35.545 Mc, respectively. The results were discussed from the viewpoint of intermolecular interaction.
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