抄録
Two complementary pictures for the resonance Raman scattering are presented, corresponding to two different ways of decomposing the four-time correlation function of dipole moment for this second-order process into a pair of two-time correlation functions. One is to take the auto-correlation of polarizability following the semi-classical picture for Raman scattering and expand it in powers of intra-system coupling; how the Raman spectra of higher orders approach the so-called luminescence is shown in the weak and strong coupling limits. Another is to study the correlation between absorption and emission processes; one can see how the relaxation of the strong coupled system after photoexcitation is reflected in the time-resolved emission spectra.
