1982 Volume 51 Issue 12 Pages 3882-3887
The electronic structures of transition metal (Fe, Ni)-metalloid (B, Si, P) alloy glasses are investigated by soft X-ray spectroscopy. In Fe-based alloy glasses a single peak is commonly observed at 4∼6 eV below the emission edges of the B Kα, Si Kβ and P Kβ spectra, while a weak hump is seen at the bottom of the main peak of the Fe Lα spectrum. Similar data are obtained for Ni-based alloy glasses. These results are consistent with recent band calculations on amorphous Fe–B and Fe–P alloys by Fujiwara, and can be explained in terms of bonding-antibonding splittings of the metalloid p bands hybridizing with the transition metal d bands. It is concluded that chemical bonding among the constituent atoms contributes to the stabilization of these metallic glasses.
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