Journal of the Physical Society of Japan
Online ISSN : 1347-4073
Print ISSN : 0031-9015
ISSN-L : 0031-9015
ESR Study of RbH3(SeO3)2 Crystals Doped with Cr3+ Ions
Chiharu TakahashiMinoru FukuiRyuji Abe
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1982 年 51 巻 3 号 p. 852-857

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ESR spectra of Cr3+ ions doped in RbH3(SeO3)2 were analysed in the paraelectric phase. The principal values and their direction cosines of D tensor were determined with D=−2800 gauss and E=−830 gauss. From the analysis of the D tensor, the doped site of Cr3+ ion and the vacant sites of H+ ions were determined. It has been also confirmed from the temperature dependences of ESR line shapes that for RbH3(SeO3)2 containing 0.1 mol% of Cr2(SO4)3·15H2O, an incommensurate phase is really existing above Tc.
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