Journal of the Physical Society of Japan
Online ISSN : 1347-4073
Print ISSN : 0031-9015
ISSN-L : 0031-9015
NMR Study of Coexistence of Ferro- and Antiferromagnetism in the Itinerant Electron System (Zr1−xNbx)Fe2. I
Yoshihiro YamadaYoshio KitaokaKunisuke AsayamaAkihiko Sakata
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1984 年 53 巻 9 号 p. 3198-3209

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Pulsed NMR investigations of 93Nb have been performed in the hexagonal Laves phase intermetallic compound (Zr1−xNbx)Fe2 with 0.8≤x≤1.0. From the measurements of the Knight shift and the nuclear spin-lattice relaxation time T1, it is demonstrated that NbFe2 is a nearly ferromagnetic compound and (Zr1−xNbx)Fe2 with x=0.95 and 0.85 are weakly ferromagnetic compounds having a Curie temperature of 30 K and 40 K, respectively, in contrast with the itinerant electron antiferromagnetism for 0.5≤x≤0.7. In the composition of x=0.8 where the antiferromagnetic order occurs below 85 K and ferromagnetic moment appears below 30 K, it was found out from T1 measurement that the system is in a coexistent state of ferro- and antiferromagnetism.
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