The Role of Column Calibration Factor in the Study of Temperature Dependence of Thermal Diffusion Factor of Hydrogenic Trace Mixtures with Helium
1987 年 56 巻 1 号 p. 105-114
詳細
1987 年 56 巻 1 号 p. 105-114
The variation of column calibration factor Fs with respect to temperature change has been attained for a given column (C.J.G. Slieker and A. E. de Vries: J. Chim. Phys. 60 (1963) 172) to estimate the temperature dependence of thermal diffusion factor αT of trace mixtures of hydrogenic isotopes in helium only to detect the existence of inelastic collision effect in the mixtures as predicted by T. K. Chattopadhyay and S. Acharyya (J. Phys. B 7 (1974) 2277). Attempts have also been made to interpret the αT’s thus obtained in terms of the available elastic and inelastic collision theories of thermal diffusion to establish the importance of the column calibration factor in column measurements.
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