1987 年 56 巻 1 号 p. 336-339
Mössbauer effect measurements of 57Fe in SrFe1−xCoxO3(0≤x≤0.5) have been performed at room temperature, 77, 64 and 4.2 K in order to study the electronic structure of Fe4+ ions. The Mössbauer spectra at 4.2 K were a single set of magnetically split lines, the form of which varied little with x. It is confirmed by the present study that Fe4+ ions have nearly a high spin electron configuration for 0≤x≤1. Mössbauer spectra at 77 K had a paramagnetic line as well as magnetically split lines in the range of 0.05≤x≤0.15, in which local fluctuation of composition of Co is considered to give rise to a magnetically inhomogeneous structure.
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