Journal of the Physical Society of Japan
Online ISSN : 1347-4073
Print ISSN : 0031-9015
ISSN-L : 0031-9015
Superconducting and Magnetic Properties of CexLa1−xMo6S8
Satoru NoguchiKiichi OkudaYasuo TakigawaMinoru YamadaMakoto HondaMuneyuki Date
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1987 年 56 巻 2 号 p. 722-730

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Superconducting and magnetic properties of the Chevrel compounds CexLa1−xMo6S8 were investigated by electrical resistance, magnetoresistance and magnetic susceptibility in a temperature range down to 0.4 K. Superconducting properties with low x are well explained by the matsuura-Ichinose-Nagaoka theory based on the Kondo effect with a range of TKTc0=0.01∼0.001. The magnetic susceptibility per mol Ce is independent of the Ce concentration and it is explained by the crystal field splitting and Kondo effect. A model of crystal field splitting which consists of three doublets with the excited energy of 10 K and 400 K in CeMo6S8 is proposed. A large negative magnetoresistance was found below 10 K for CeMo6S8. Magnetic and superconducting phase diagram of CexLa1−xMo6S8 was determined.
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