抄録
In order to improve adhesiveness of silicon rubber with acrylic resin, we tried to prepare a acrylic ester monomer containing Si-CH=CH2 group. It was found that the reaction of chloromethyl dimethyl vinyl silan (CMDMVS) with sodiumm methacrylate (NaMA) at 50°C in DMSO for 18h gave MMDMVS in 78% yield. Further, the copolymerization of methyl methacrylate (MMA) with MMDMVS in the presence of azobisisobutyronitrile at 80°C for 7h in THF gave corresponding copolymer in which contains Si-CH=CH2 group.
