Journal of Advanced Science
Online ISSN : 1881-3917
Print ISSN : 0915-5651
ISSN-L : 0915-5651
Thermodynamic stability of hydride of AB5-type alloys and their dissolution behavior in KOH
Shigeki NAKAYAMAToshiro KUJIHiroaki NAKANO
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2001 Volume 13 Issue 1-2 Pages 56-57

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Abstract
The empirical equation, based on electronegativities and atomic sizes of constituent elements, for the estimation of the thermodynamic stability of hydride of AB5-type alloys was proposed. The equation can estimate the plateau pressure of PC isotherms with a reliability higher than 99.8%. Moreover, it is found that the deviation of plateau pressure from the estimated value describes the phase segregation in alloy morphology. In this research the dissolution behaviors of alloys in a KOH solution were also discussed in relation to the phase segregation.
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