熱測定
Online ISSN : 1884-1899
Print ISSN : 0386-2615
ISSN-L : 0386-2615
解説
YSZ 多結晶体の熱伝導特性へ与える欠陥構造の影響
佐々木 一哉
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ジャーナル フリー

2013 年 40 巻 2 号 p. 65-70

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抄録
Based on author's research data obtained by using microstructure-controlled sintered dense yttria–stabilized zirconia (YSZ) pellets and porous YSZ pellets, influence of defect structure on the thermal conduction characteristic of dense YSZ polycrystalline and porous YSZ polycrystalline is explained. The difference in the specific heat capacity between 3YSZ (Y2O3/ZrO2 = 3/97 (mol)) and 8YSZ (Y2O3/ZrO2 = 8/92 (mol)) is discussed from the point of view of the number of lattice defects introduced to YSZ by doping Y2O3. Thermal diffusivity in a high temperature region and a low temperature region is explained separately, respectively. Contributions of phonon diffusion and photon heat radiation in YSZ grain and pore to temperature dependency of the thermal diffusivity of 3YSZ and 8YSZ are clarified. In order to interpret their contributions, porosity, pore size, and grain–boundary concentration are used as a key factor.
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© 2013 日本熱測定学会
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