熱測定
Online ISSN : 1884-1899
Print ISSN : 0386-2615
ISSN-L : 0386-2615
解説
プルシアンブルー薄膜への電気化学的な正孔注入とその磁気応答
野口 真理子
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ジャーナル フリー

2019 年 46 巻 4 号 p. 188-194

詳細
抄録
Recently the electrical switching of magnetization and magnetic properties have been attempted by many researchers for the application to practical devices. This review introduces a significant magnetic response of Prussian Blue (PB) thin film incorporated in an ionic-liquid electrolysis cell by applying a DC bias voltage. Electrochemical hole doping into the PB film oxidized FeII to FeIII ions in the film, providing quasi-reversible electrochromic behaviour. We performed magnetic measurements of the electrolysis cell under a DC bias on an SQUID magnetometer. The switching of the film from a paramagnet to a ferrimagnet with a magnetic response at low temperatures and an in situ enhancement of magnetization of the film at 300 K were demonstrated.
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