The Review of High Pressure Science and Technology
Online ISSN : 1348-1940
Print ISSN : 0917-639X
ISSN-L : 0917-639X
Series of Reviews for Hydrogen and Pressure (5)
Explanation of "the Mysteries of Water" by a Liquid-Liquid Critical Point
Osamu MISHIMA
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2007 Volume 17 Issue 4 Pages 352-356

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Abstract
According to the liquid-liquid critical point hypothesis of water, liquid water separates into low- and high-density liquid phases at low temperature and high pressure, and these liquid phases become the known low- and high-density amorphous ices below their glass transition temperatures. An accumulation of experimental and theoretical results seems to support this hypothesis, and this hypothesis may virtually explain "the mysteries of water" including the density maximum at 277 K. Aqueous solutions and the confined water appear to be readily interpreted on the hypothesis.
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© 2007 The Japan Society of High Pressure Science and Technology
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