高圧力の科学と技術
Online ISSN : 1348-1940
Print ISSN : 0917-639X
ISSN-L : 0917-639X
特集:配列ナノ空間物質の高圧科学
ホウ素クラスター固体と高圧科学
白井 光雲
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ジャーナル フリー

2012 年 22 巻 1 号 p. 33-43

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  A review is given for the properties of boron and boron-rich solids, whereas the special roles of high pressure research are emphasized through recent progresses in this exotic material. The topics discussed encompass phase transitions, metal/insulator transition, and doping issue. Hardness and internal flexibility along with electron deficiency are key characters of boron solids. The direct metal-transition by band overlap which α-boron exhibits at high pressure is understood on this ground. Characterizing materials from electronic stiffness and internal degree of freedom provides a good guideline for high-pressure material researches.
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© 2012 日本高圧力学会
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