高圧力の科学と技術
Online ISSN : 1348-1940
Print ISSN : 0917-639X
ISSN-L : 0917-639X
特集:高圧流体の物性と反応
20℃,高圧力下の液相領域におけるジメチルエーテル+エタノール混合系の体積挙動
保科 貴亮大矢 浩平秋葉 淳辻 智也日秋 俊彦
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2013 年 23 巻 4 号 p. 319-324

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Densities of dimethyl ether (DME)+ethanol liquid mixtures were measured at 20℃ under high pressure up to 40 MPa. Densities of DME+ethanol mixtures decreased with increasing DME and increased with increasing pressure at 20℃. The composition dependence of the excess molar volumes showed concaved shape and had a minimum around 50 mol% of DME at any pressures studied. The hydrogen bond between the oxygen of a DME molecule and the −OH group of an ethanol molecule makes an important role in the volume change in DME+ethanol liquid mixtures at 20℃ under high pressure.
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© 2013 日本高圧力学会
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