高圧力の科学と技術
Online ISSN : 1348-1940
Print ISSN : 0917-639X
ISSN-L : 0917-639X
Infrared Spectra of D2O Ice under Pressure
H. YamawakiM. SakashitaH. FujihisaK. Aoki
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ジャーナル フリー

1998 年 7 巻 p. 1135-1137

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Infrared absorption spectra of D2O ice were measured up to 140 GPa. The O-D stretching frequency rapidly decreases with pressure toward zero. The transition pressure, which could be defined as a pressure where the stretching frequency becomes zero, in D2O ice was determined to be 94 GPa. This transition pressure is higher by 26 GPa than that in H2O ice. A large difference in the transition pressure may be attributed to anharmonic contribution to the potential and consequently to the stretching vibrations.
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© The Japan Society of High Pressure Science and Technology
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