高圧力の科学と技術
Online ISSN : 1348-1940
Print ISSN : 0917-639X
ISSN-L : 0917-639X
Synthesis of Azetidines from Imines with 2, 3-Dihydrofuran under High Pressure
A. OishiY. TaguchiT. TsuchiyaI. Shibuya
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ジャーナル フリー

1998 年 7 巻 p. 1253-1255

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抄録
6, 7-Aryl-2-oxa-7-azabicyclo[3. 2. 0]heptane compounds were obtained from arylimines with 2, 3-dihydrofuran under high pressure. When benzylidene aniline used as imine, 6, 7-diphenyl-2-oxa-7-azabicyclo[3. 2. 0]heptane was obtained 66% yield with 87% selectivity. This reaction was promoted by pressure and the yield and the selectivity of the reaction were increased by temperature. The mechanism of the reaction was considered zwittenonic route was favored.
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© The Japan Society of High Pressure Science and Technology
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