Organic Reactions at High Pressure
キーワード:
Cycloadditions,
packing coefficients,
product selectivity,
supramolecules,
thermally labile compounds,
peptide coupling
1998 年 8 巻 2 号 p. 104-110
詳細
1998 年 8 巻 2 号 p. 104-110
The utility of high pressure for the understanding of chemical reactions and its applications in organic synthesis is demonstrated for pericyclic reactions (cycloadditions, Cope rearrangements, electrocyclizations and intramolecular Diels-Alder reactions). With the example of the peptide coupling it is shown that pressure is a valuable tool for the control of other reactions than pericyclic reactions, too.
