Abstract
Poly (vinyl alcohol) (PVA) hydrogel with high water content is the candidate material for artificial cartilage. PVA hydrogels prepared by freeze-thawing (FT) method (PVA-FT gel), cast-drying (CD) method (PVA-CD gel) and hybrid method of FT and CD (PVA-hybrid gel) were developed and their friction and wear behaviors were evaluated. Sliding pairs of a Cobalt-chromium-molybdenum (Co-Cr-Mo) alloy or alumina ceramic ball and a PVA hydrogel plate were tested in reciprocating friction test. In this study, ultra-pure water and simulated synovial fluid were used as lubricants for friction test. PVA-FT gel showed high friction and severe wear in ultra-pure water. Friction coefficient of PVA-CD gel in ultra-pure water was quite low such as about 0.005, but scratches were observed on the surface of PVA-CD gel. PVA-hybrid gel lubricated in ultra-pure water showed low friction such as 0.004, and intact surface structure of PVA-hybrid gel remained after friction test. Simulated synovial fluid contributed to the improvement of lubrication property of all PVA hydrogels and PVA-hybrid gel showed the lowest friction coefficient such as 0.003 and minimum wear. These results indicated that the hybridization of FT and CD method improved the lubrication property of PVA hydrogel, and PVA-hybrid gel has a great potential as the material for artificial joint.
