Abstract
In this study, we investigated the density fluctuation of diatomic fluids around the critical points for evaluation of the principle of corresponding state. We used Molecular Dynamics (MD) simulation against the 2-Center Lennard-Jones (2CLJ) fluids for extraction of structure of fluctuation around the critical points. We evaluated the density fluctuation by two methods. One is the dispersion of number of molecules at certain domain as time-averaged quantity. The other is the calculation of static structure factor. As the results, in 2CLJ fluids that have shorter molecular elongations comparatively, the principle of corresponding state is satisfied because of the small difference in the fluctuation structure extracted by the present two methods.
