低Si/Al比アルミノシリケート硬化体の作製に向けたSi-Alゲルの合成

抄録

An aluminosilicate solid is an inorganic material that has the property of immobilizing heavy metals or radionuclides in the matrix. In this study, aluminosilicates with a Si / Al molar ratio of 0.5 was synthesized from a chemical reagent in order to produce aluminosilicate solids with a low Si / Al molar ratio, which were expected to improve the immobilization of heavy metals and radionuclides contained in the matrix. The synthesized Si-Al gel with a Si / Al molar ratio of 0.5 had little impurity content and was in an amorphous phase. In addition, the compressive strength of the aluminosilicate solid produced by the synthesized Si-Al gel showed a 5 MPa or more, confirming that it can be used as a raw material for aluminosilicate solids. The aluminosilicate solid with a Si/Al molar ratio of 1.25 had a dense surface structure from the result of BSE images and had the highest compressive strength among all samples.