journal of the Japan Society for Testing Materials
Print ISSN : 0372-7971
Studies on the Graphite Electrode (Fourth Report)
Swelling and corrosion of graphite anodically attacked by sulphate ions
Shinzo OKADAShiro YOSHIZAWATadao ISHIKAWA
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1958 Volume 7 Issue 53 Pages 111-113

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Abstract
The influences of current density, temperature, and acidity of electrolyte on the swelling and the corrosion of anode graphite which was anodically attacked by sulphate ions, were studied. The corrosion of graphite caused by swelling was found to be minimum at the following conditions; 3 to 5amp./dm2., above 50°C, and acidity of the electrolyte below 1N.
From the above results, it was confirmed that the corrosion of anode graphite in electrolysis of sodium chloride solution on the amalgam process was not caused by the swelling due to the sulphate ions contained as impurities in electrolyte, but to the anodic oxidation.
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© by The Society of Materials Science, Japan
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