Journal of Water and Environment Technology
Online ISSN : 1348-2165
ISSN-L : 1348-2165
Original Articles
Copper Aluminum Layered Double Hydroxide Modified by Biochar and its Application as an Adsorbent for Procion Red
Neza Rahayu PalapaNovie JuleantiNormahRisfidian MohadiTarmizi TaherAddy RachmatAldes Lesbani
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JOURNAL OPEN ACCESS

2020 Volume 18 Issue 6 Pages 359-371

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Abstract

The preparation of a copper aluminum/biochar composite and its application for the adsorption of procion red dye was studied. The composite materials were prepared by a co-precipitation method and characterised by X-ray diffraction, Fourier-transform infrared spectroscopy, Brunauer-Emmett-Teller surface area analysis, scanning electron microscopy, and thermogravimetry. The results of the adsorption study show that adsorption on the copper aluminum/biochar composite follows pseudo-second-order kinetics, and the adsorption isotherm of procion red conforms to the Langmuir isotherm model. The Langmuir fitting result for the maximum adsorption quantity of procion red on copper aluminum/biochar composite is 175.439 mg/g, which is higher than copper aluminum layered double hydroxide. The thermodynamic analysis suggests that procion red adsorption is spontaneous (standard free energy < 0) and endothermic and involves a random solid–liquid phase interface. The composite materials exhibited good recycling performance.

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© 2020 Japan Society on Water Environment

This is an open-access article distributed under the terms of the Creative Commons Attribution (CC BY) 4.0 License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
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