Abstracts of Symposium on Physical Organic Chemistry
21st Symposium on Physical Organic Chemistry
Session ID : 3P90
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Shape-controllable gold nanocrystallization using an amphiphilic polythiophene; the preparation and characterization
Tsuyoshi MinamiRyuhei NishiyabuMasahiko Iyoda*Yuji Kubo
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Abstract
Polythiophenes incorporating gold nanocrystals have great promise for applications in organic electronics. To that end, we investigated gold nanocrystallization in the presence of an isothiouronium-attached amphiphilic polythiophene. It was found that reducing agent-free nanocrystallization occurred upon addition of HAuCl4; the microenvironment produced by the amphiphilic polythiophene controlled the shape of the crystals generated. Furthermore, the conductivity of the obtained polythiophene-gold nanoparticle hybrids were evaluated.
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© 2011 by The Society of Physical Organic Chemistry, Japan
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