Abstracts of Symposium on Physical Organic Chemistry
21st Symposium on Physical Organic Chemistry
Session ID : A23
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Imine-bridged Rotaxanes: Structural Effects on Mobility Control, and Exploration toward Multi-interlocked Systems.
*Hiroyoshi Sugino, Hidetoshi Kawai, Takeshi Umehara, Kenshu Fujiwara, Takanori Suzuki
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Keywords: Rotaxanes, Imine, Dynamic covalent bond, Molecular switch, Interlocked molecules
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Abstract
We have previously reported a novel rotaxane synthesis based on imine-bond formation between an axle molecule and a ring molecule, for which we can control the subunit mobility through reversible inverconversion between imine-bridged rotaxane and [2]rotaxane. Here we report structural effects of axle and ring units on mobility control, and preparation of [n]rotaxanes by degenerating the imine-bridged pseudorotaxane.
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© 2011 by The Society of Physical Organic Chemistry, Japan
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