Abstracts of Symposium on Physical Organic Chemistry
21st Symposium on Physical Organic Chemistry
Session ID : B04
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Synthesys and Dynamic Property of Molecular Helix with an Extremely High pi-Electron Density
*Eisuke OHTA, Hiroyasu SATOH, Shinji ANDO, Atsuko KOSAKA, Yuki SUNA, Takanori FUKUSHIMA, Daisuke HASHIZUME, Takuzo AIDA
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Keywords: o-Phenylene, pi-Conjugated Polymer, Molecular Helix, Helicity, Dynamic Property
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Abstract
o-Phenylene is an elusive class of pi-conjugated polymers due to its synthetic difficulty. We have successfully established the method for synthesis of long-chain o-phenylene oligomers and polymers. The structures and dynamic behaviors of the new pi-system will be discussed.
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© 2011 by The Society of Physical Organic Chemistry, Japan
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