Abstracts of Symposium on Physical Organic Chemistry
22nd Symposium on Physical Organic Chemistry
Session ID : 2P172
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Poster Session (The 2nd day)
Preparation and properties of diacridine/diacridinium compounds possessing a spacer with different rigidity.
Takanori Suzuki*Yuuki HoshiyamaHidetoshi KawaiFujiwara Kenshu
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CONFERENCE PROCEEDINGS FREE ACCESS

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Abstract
Dichromophoric motifs exhibit special properties which the corresponding monochromophoric counterpart does not. Such properties largely depends on the distance and relative orientation of two chromophores. 9-Phenylacridine and 10-methyl-9-phenylacridinium have been known for their redox activity and fluorescent properties. We studied the compounds having two 9-phenylacridines and 10-methyl-9-phenylacridiniums, which are linked by a spacer with different rigidity. The rigidity of spacers affects their spectra properties and redox behaviors, whose details will be reported.
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© 2011 by The Society of Physical Organic Chemistry, Japan
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