抄録
The gas chromatographic resolution of isoborneol and borneol enantiomers were achieved by capillary column coated with chiral stationary phase. The gas chromatography/chemical ionization mass spectrometry (GC/CIMS) were performed using (S)-(+)-1-amino-2-propanol, (R)-(−)-1-amino-2-propanol, (S)-(+)-2-amino-1-propanol, and (R)-(−)-2-amino-1-propanol as chiral reagent gases. The CI mass spectra could be obtained with good reproducibilities. It was found that the CI mass spectra of the enantiomers could be distinguished when a chiral reactant ion attached to a chiral functional group of the sample molecule.
