Journal of the Mass Spectrometry Society of Japan
Online ISSN : 1880-4225
Print ISSN : 1340-8097
ISSN-L : 1340-8097
n-アルカンの質量スペクトルに現われるCC結合およびCH結合の切断の割合
鴫 和雄山本 正夫広田 鋼蔵
著者情報
ジャーナル フリー

1973 年 21 巻 3 号 p. 223-228

詳細
抄録
It is indicated that from the mass spectra of several n-alkanes the ion groups formed through the processes explained by QET and those by MOT exist. The ion group containing the same carbon numbers and the ion produced from only CC-bond scission in that ion group vs. the changes of Ve were adjusted, respectively. From the results, it is noted that the produced ions are explained by QET as the range of Ve was from IP to IP+D(CC), most of the ions are explained by MOT as from IP+D(CC) to 20V(∼30V), and the ions resulting from the successive scissions caused by the excess energies are added as over 20V(∼30V).
著者関連情報
© 日本質量分析学会
前の記事 次の記事
feedback
Top