Penning Ionization Processes Studied by Electron Spectroscopy

Andrew J Yencha

doi:10.5702/massspec1953.27.135

著者情報

キーワード: Penning ionization electron spectroscopy, Photoelectron spectroscopy, Energy transfer processes, Metastable rare gas atoms, Particle-particle collision dynamics, Ionization potentials

ジャーナルフリー

1979 年 27 巻 3 号 p. 135-156

DOI https://doi.org/10.5702/massspec1953.27.135

詳細

Published: 1979/09/30 Received: 1979/07/25 Available on J-STAGE: 2010/06/28 Accepted: - Advance online publication: - Revised: -
訂正情報
訂正日: 2010/06/28 訂正理由: - 訂正箇所: 著者情報訂正内容: Wrong : Andrew J Yencha¹⁾
Right : Andrew J Yencha

訂正日: 2010/06/28 訂正理由: - 訂正箇所: 所属機関情報訂正内容: 訂正前 :
1) This article is adapted from the text of a lecture given by the author at the 26th annual meeting of the Mass Spectroscopy Society of Japan

訂正日: 2010/06/28 訂正理由: - 訂正箇所: キーワード情報訂正内容: Wrong : Penning ionization electron spectroscopy Photoelectron spectroscopy Energy transfer processes Metastable rare gas atoms Particle-particle collision dynamics Ionization potentials
Right : Penning ionization electron spectroscopy, Photoelectron spectroscopy, Energy transfer processes, Metastable rare gas atoms, Particle-particle collision dynamics, Ionization potentials

訂正日: 2010/06/28 訂正理由: - 訂正箇所: 引用文献情報訂正内容: Wrong : E
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J. A. Ratcliffe, Physics of the Upper Atmosphere, Academic Press, New York, 1960.
J. W. McGowan, The Excited State in Chemical Physics, Advances in Chemical Physics, Vol. 28, Wiley-Interscience, New York, 1975.
D. H. Stedman and D. W. Setser, Prog. Reaction Kinetics, 6, 193(1971).
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M. F. Golde, Gas Kinetics and Energy Transfer, eds. P. G. Ashmore and R. J. Donovan, Specialist Periodical Reports, The Chemical Society, London, Vol. 2,p.123,1977.
G. W. F. Drake, Phys. Rev. A, 3,908(1971).
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V. Cermák and A. J. Yencha, J. Electron Spectry. Relat. Phenom., 11,67(1977).
The relative population density of He(I)photons and He(21S, 23S)metastable species can be estimated, for example, from the measured EEDC for argon as given in Fig. 1of Ref. 32.
R. E. Bolden and N. D. Twiddy, Faraday Discussions Chem. Soc., 53,192(1972).
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For additional examples see refs. 19and20and references therein.
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Since this paper has dealt primarily IA ith the concepts of Penning ionization electron spectroscopy, readers who are further interested in specific experimental details are referred to the paper by V. Cermak and J. B. Ozenne, Int. J. Mass Spectrom. Ion Phys., 7,399(1971).

抄録

The technique of measuring the kinetic energy of electrons ejected from atomic or molecular species as a result of collisional energy transfer between a metastable excited rare gas atom and an atom or molecule is known as Penning ionization spectroscopy. Like the analogous photoionization process of photoelectron spectroscopy, a considerable amount of information has been gained about the ionization potentials of numerous molecular systems. It is, in fact, through the combined analyses of photoelectron and Penning electron spectra that affords a probe of the particle-particle interactions that occur in the Penning process. In this paper a short survey of the phenomenon of Penning ionization, as studied by electron spectroscopy, will be presented as it pertains to the ionization processes of simple molecules by metastable excited atoms.

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