2004 Volume 45 Issue 4 Pages 1060-1064
For many years, many researchers had taken it for granted that the martensitic phase of Ni2MnGa was the tetragonal structure. The common knowledge as regads the magnetic moment of the Heusler alloys including Mn was around 4.0 μB per formula unit (f.u.). However, Brown et al. newly observed the super-cell structure as the martensitic phase and reported the small magnetic moments on Mn in Ni2MnGa. In this paper, the electronic structures are calculated and magnetic moments are estimated for Ni2MnGa in the L21 and martensitic super-cell structures. In our calculation, we obtained a variety of magnetic moments on Mn in the martensitic structure and that values are largely different each other.