MATERIALS TRANSACTIONS
Online ISSN : 1347-5320
Print ISSN : 1345-9678
ISSN-L : 1345-9678
Local Structural Analysis on Decomposition Process of LiAl(ND2)4
Kazutaka IkedaToshiya OtomoHidetoshi OhshitaNaokatsu KanekoMasami TsubotaKentaro SuzuyaFumika FujisakiTaisuke OnoToshiyuki YamanakaKeiji ShimodaTakayuki IchikawaYoshitsugu Kojima
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2014 年 55 巻 8 号 p. 1129-1133

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Local structural changes that accompany amorphization during the decomposition of LiAl(ND2)4 were investigated by neutron total scattering measurements. Structure factors before the decomposition were attributed to single-phase LiAl(ND2)4 characterized by isolated [ND2] units. Atomic pair distribution functions after heat treatments at 433 and 673 K showed that LiAl(ND2)4 decomposed to amorphous mixed phases that contain Li3AlN2 and AlN.

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© 2014 The Japan Institute of Metals and Materials
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