Interface Formation Mechanism of Cemented Carbide Dipped in Molten Cast Iron

抄録

When cemented carbide contacts molten cast iron during the insert casting process, the binder phase of the cemented carbide is thought to melt even if the molten temperature of the cast iron is lower than the solidus temperature of the cemented carbide (1593 K). It is important to understand the melting mechanism to clarify the interface formation mechanism, and subsequently control the interface structure. The purpose of this study is to clarify the interface formation mechanism from the microstructural change of cemented carbide dipped in molten cast iron. A round bar specimen made of cemented carbide was dipped in molten cast iron at 1473 to 1596 K, and pulled up after a predetermined time. Microstructure observation, elemental analysis, and hardness test were performed on the cross-section of the specimen. The specimen changed from a homogeneous sintered structure to a two-layer structure, the center side was a non-reacted layer that did not change, and the outer side was the transition layer where melting had occurred. The diffusion of Fe and C is thought to have decreased the solidus temperature of the binder phase significantly that the binder phase melted. The non-reacted layer radius could be expressed by the rate equation derived from the Nernst-Brunner equation. Structural changes were seen at the interface such as increased outer diameter of the cemented carbide round bar specimen, occurrence of shrinkage cavities in the transition layer, and characteristic concentration of Co at the boundary. These are thought to be due to liquid phase migration occurring in the molten binder phase and decreased WC solubility due to increase in Fe concentration.

 

This Paper was Originally Published in Japanese in J. JFS 93 (2021) 67–73. The background, experimental procedures, results, and discussion have been revised.