2024 年 65 巻 4 号 p. 362-367
The topological and chemical short-range ordering (TSRO and CSRO) of Pd82Ge18 amorphous alloys prepared by the single-roll liquid quench method were analyzed using a combination of anomalous X-ray scattering and reverse Monte Carlo (RMC) simulation. The degree of development of TSRO and CSRO in the amorphous structure model made with the RMC simulation (RMC model) was evaluated by comparison with the dense random packing model (DRP model) calculated using metallic and covalent atomic radii. In the RMC model, a shortening of the Pd–Ge nearest neighbor correlation and a decrease in the coordination number around Ge were observed. Voronoi polyhedral analysis was performed to evaluate the local geometrical structure around the Pd and Ge atoms. Although the DRP structure can reasonably approximate the local structure around the Pd atoms, the TTP structure corresponding to the local structure in crystalline Pd2Ge develops around the Ge atoms as a characteristic TSRO. However, the preferential coordination of Pd atoms around Ge, which is a CSRO associated with the TTP structure in the crystalline phase, was not observed. These results indicate that strong CSRO does not necessarily accompany the TTP structures in metal-semimetal amorphous alloys.
