Alloy Design and Fabrication of Ingots of Al–Mg–Li–Ca Light-Weight Medium Entropy Alloys

抄録

Alloy designs of light-weight high and medium entropy alloys (LW-HEA and LW-MEA, respectively) are discussed in relation to solving the problem of the empirical alloy parameter, ΔH_mix, and the difficulties of the fabrication process. The ingots of newly-designed Al–Mg–Li–Ca LW-MEAs were fabricated by the conventional casting process via crucible melting without using a vacuum furnace, and casting under air atmosphere. The ΔH_mix parameter is the average value of the mixing enthalpy of ΔH_i-j between the two components, i-j, in the multicomponent alloys, and the dispersion of ΔH_i-j cannot be evaluated. The parameter δ(ΔH_mix) was suggested for the evaluation of the dispersion of ΔH_i-j. The Al–Mg–Li–Ca LW-MEAs were designed based on the empirical alloy parameters, including δ(ΔH_mix). The alloy ingots of equiatomic AlMgLiCa, non-equiatomic Al₂MgLiCa, and AlMgLiCa_0.3 were successfully obtained by the conventional casting process. The solidification microstructure of the ingots in the Al₂MgLiCa LW-MEA was investigated, with particular focus on the position dependences of the chemical composition, constituent phases, solidification microstructure, and hardness. The present study clarified that LW-HEAs and LW-MEAs containing Al, Mg, Li, and Ca can be obtained by the conventional casting process under air atmosphere, without specific expensive casting equipment.

 

This Paper was Originally Published in Japanese in J. JFS 91 (2019) 717–729. Minor corrections in abstract, main text, figure and table captions, and references were performed with translation from Japanese to English and proof reading by native speakers. Some references written in Japanese was replaced by the related references written in English: Ref. 11) was changed from “the 24th Committee on casting of Japan Society for the Promotion of Science (JSPS), Subcommittee on casting process, the 20th meeting document, No. 22 (2018) 1–5.” to “Mater. Des. 184 (2019) 108172”. Ref. 41) was changed from “J. Soc. Mater. Sci., Japan 68 (2019) 205–211.” to “Mater. Trans. 61 (2020) 311–317”.