Dissolution of Magnesium from Serpentine Mineral in Sulfuric Acid Solution

抄録

As the volume of CO₂, one of greenhouse gases linked to global warming, in the atmosphere increases, there has been an increasing interest in CO₂ sequestration. Aqueous carbonation, which involves the extraction of Mg from serpentine minerals and the subsequent carbonation reaction with CO₂ to form the geologically stable mineral MgCO₃, has been proposed as a promising CO₂ sequestration technology. This study investigates the dissolution of Mg from serpentine mineral in H₂SO₄ solution. The study is part of a major research project aimed at developing an effective CO₂ sequestration technology using the serpentine mineral which is readily available in Korea. Complete dissolution of Mg from natural serpentine was achieved in 30 min at a temperature of 90°C under 0.5 M H₂SO₄. The rate of dissolution of Mg was independent of the agitation speed at speeds above 300 rpm. The fraction of Mg dissolved from milled serpentine was found to be a little higher than that from natural serpentine up to 70°C in 0.5 M H₂SO₄. The Jander equation was used to explain the dissolution rate data. The rate of Mg dissolution seemed to be limited by diffusion through the thin channels formed between the silica layers in the serpentine particles.