MATERIALS TRANSACTIONS
Online ISSN : 1347-5320
Print ISSN : 1345-9678
ISSN-L : 1345-9678

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Electromotive Force of Gas Concentration Cell Using Alumina-Rich Nonstoichiometric Magnesium Aluminate Spinel as the Solid Electrolyte
Yuji OkuyamaNoriaki KuritaNorihiko Fukatsu
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ジャーナル 認証あり 早期公開

論文ID: MER2007243

この記事には本公開記事があります。
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The following gas concentration cell, was constructed and the electromotive force was measured in the temperature range from 1373 to 1673 K. When the oxygen partial pressure on both electrodes was kept at a constant value, hydrogen partial pressure difference on the electrodes did not give any significant electromotive force at the experimental temperatures. When the hydrogen partial pressures were kept at a constant value on both electrodes, the electromotive force dependent on the difference of the oxygen partial pressure on the electrodes was obtained. The electromotive force was in agreement with the theoretical value calculated on assumption that the activity of magnesia was kept constant throughout in the electrolyte and that the transport number of cation was unity.
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© 2008 The Japan Institute of Metals and Materials
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