Abstract
The e.m.f. of the cell Tl(l)/TlCl in KCl-LiCl/Ti-Bi(l) was measured over the temperature range of 370° to 480°C. The activity curve shows a profoundly negative deviation from Raoult’s law. The excess thermodynamic functions were calculated from the activity data obtained. Theoretical consideration was given for the excess functions of this system.
