Transactions of the Japan Institute of Metals
Online ISSN : 2432-4701
Print ISSN : 0021-4434
ISSN-L : 0021-4434
The Stability of HCP Cobalt Prepared by a Vacuum Deposition Method
J. Echigoya, M. Nemoto, H. Suto
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1980 Volume 21 Issue 4 Pages 181-190

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Abstract
The crystal structure of cobalt deposits on various metal substrates has been examined by transmission electron microscopy. The cobalt deposits on (001)-Fe substrates exhibited the hcp structure, while those on (001)-Ag substrates exhibited the fcc structure. On (001)-Au substrates, the cobalt exhibited the hcp+fcc structures at substrate temperatures below the transformation temperature.
These observations are explained from the value of c⁄a ratio of the cobalt deposits. The reduction of c⁄a ratio stabilizes the hcp structure. This conclusion is supported by the experiments of cobalt deposition on (111)-metal substrates.
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