Transactions of the Japan Institute of Metals
Online ISSN : 2432-4701
Print ISSN : 0021-4434
ISSN-L : 0021-4434
The Stability of HCP Cobalt Prepared by a Vacuum Deposition Method
J. EchigoyaM. NemotoH. Suto
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ジャーナル フリー

1980 年 21 巻 4 号 p. 181-190

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The crystal structure of cobalt deposits on various metal substrates has been examined by transmission electron microscopy. The cobalt deposits on (001)-Fe substrates exhibited the hcp structure, while those on (001)-Ag substrates exhibited the fcc structure. On (001)-Au substrates, the cobalt exhibited the hcp+fcc structures at substrate temperatures below the transformation temperature.
These observations are explained from the value of ca ratio of the cobalt deposits. The reduction of ca ratio stabilizes the hcp structure. This conclusion is supported by the experiments of cobalt deposition on (111)-metal substrates.
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