Online ISSN : 1884-6440
Print ISSN : 0385-1036
ISSN-L : 0385-1036
特集:人工膜シンポジウム2「ナノファイバー・ナノ空間を利用した分離膜の新展開」
ポリジメチルシロキサン膜の多孔構造制御と 低圧膜ろ過による有機溶媒回収
清野 竜太郎
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ジャーナル オープンアクセス

2021 年 46 巻 4 号 p. 209-214

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Making membrane porous could reduce the energy consumption of the membrane processes. Porous polydimethylsiloxine (PDMS) membranes were prepared using polyethylene glycol (PEG) or propylene glycol (PG) as pore forming agent (PFA). After the PDMS/PFA membranes were prepared, they were immersed in warm water to remove PFA from the membranes to prepare the PDMS porous membranes. Symmetric porous PDMS membrane was obtained when PEG was used as PFA. However, asymmetric porous membrane having a dense PDMS layer on one surface was prepared when PG was used as PFA. The porosity of the membranes increased with PFA content. The solvent permeation across the membranes was measured by low–pressure (0.2 MPa) driven filtration. Three kinds of ink solutions (green, blue and white) containing fine solid particle and organic solvent were used as feed solutions. The permeation increased with increasing the PFA content. The solid particle weight concentrations in ink solutions were about 10 wt%, however, almost pure solvent was obtained for all the ink solutions by the filtration when the membranes prepared using PG as PFA.
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