Mineralogical Journal
Online ISSN : 1881-4174
Print ISSN : 0544-2540
ISSN-L : 0544-2540
Mössbauer spectra of synthetic and natural calium-rich clinopyroxenes
Yoshito MATSUIYasuhiko SYONOYonezo MAEDA
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1972 年 7 巻 1 号 p. 88-107

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Mössbauer spectra have been measured at room temperature on synthetic samples along the join CaMgSi2O6-CaFeSi206 and the join Ca0.8Mg1.2Si2O6-CaO.8Fe1.2Si206, as well as on natural samples including ferrosalites, augites, and subcalcic augite. Only those samples of which compositions lie upon the Di-Hd join gave simple spectra. Substitution of the types Ca-(Mg, Fe2+) and (Mg, Fe2+)-(Fe3+, Al) makes the spectrum complex, so that the observed curve cannot be analyzed in terms of two doublets for Fe2+, even when we cannot expect more than two sets of nonequivalent positions for Fe2+ from X-ray crystallographic data.
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© Japan Association of Mineralogical Sciences
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