2019 年 3 巻 1 号 p. 19-23
The structural and magnetic properties of (Sm,Y)(Fe,Co)12-xTix (x = 0.5, 0.6) prepared by arc melting and rapid quenching are investigated. The formation of the TbCu7-type phase were facilitated with decreasing amount of Ti concentrations, and many amount of TbCu7-type phase was observed for arc melted alloy at low Ti concentrations (x = 0.5). In the contrast, the volume fraction of TbCu7-type phase was reduced remarkably for rapidly quenched alloy. This shows that the formation of the ThMn12 structure was facilitated by rapid quenching at low Ti concentrations. When compared with the same amount of Ti concentrations (x = 0.5), the value of saturation magnetization of rapidly quenched alloy which was 1.55 T was higher than that of arc melted alloy.