Journal of the Society of Inorganic Materials, Japan
Online ISSN : 2185-4378
ISSN-L : 1345-3769
塩化物含有飛灰から重金属の回収およびセメント原料への資源循環処理
三浦 啓一鈴木 務大神 剛章井田 雅也橋本 和明戸田 善朝
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2000 年 7 巻 289 号 p. 721-728

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In recent years, amount of urban waste is increasing and a shortage of land disposal site has been caused as a serious problem. The study was carried out to establish recycling process of fly ash included with chloride without generating any secondary waste. The following summarized the results.
Chloride in the fly ash was leached with water. We can downsize facilities for subsequent process, because volume of residue was reduced by 1/5 to 1/10.
Copper and zinc ions in the residue were leached with sulfuric acid solution. From this filtrate, copper metal was recovered by cementation and zinc hydroxide was recovered by adjustment pH, respectively.
Lead ion was leached with aqueous solution of sodium hydroxide and was recovered as lead sulfide. At the same time, calcium sulfate was converted to calcium hydroxide which was able to be utilized as a raw material for cement.
The waste water caused from this process could be content with effluent standard by water treatment attaching importance to de-selenium processing.
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