五塩化アンチモンによるイソヘキサンの重合
1974 年 1974 巻 5 号 p. 990-992
詳細
1974 年 1974 巻 5 号 p. 990-992
Polymers of isohexane were formed by the addition of antimony pentachloride to isohexane. In polar solvent the rate of this reaction was accelerated.Apparent activation energy was 4.0kcal/mol which was lower than that of ordinary porymerization.
The structure of the polymer was studied by IR and NMR spectroscopies, and the polymerization mechanism was discussed.
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